Google looks to be testing, or maybe it is a bug, capitalizing the URL or breadcrumb part of the snippets in the search results. I see a number of folks on Twitter chatting about it and I have numerous screen shots of this in action.
Here are some screen shots Chris Jones from Screaming Frog sent me via email showing with the capitalization and without.
With Capitalization:
Without Capitalization:
Here are more screen shots from Twitter:
There are even complaints about this in the Google Webmaster Help forums.
Do you see this?
Forum discussion at Google Webmaster Help.